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Wilhelmy studied at Heidelberg, earning a doctorate in 1846. He worked as a Privatdozent from 1849 to 1854 before moving to Berlin.
Wilhelmy's work in chemical kinetics concerned the acid-catalyzed conversion of a sucrose solution into a 1:1 mixture of fructose and glucose, a reaction that he followed with a polarimeter. He wrote a differential equation to describe the reaction, integrated it, and used it to interpret his experimental results. Wilhelmy found that the reaction's rate was proportional to the concentrations of sucrose and of acid present. He also examined the influence of temperature on the reaction.
According to Moore, Wilhelmy received little credit from his contemporaries for his early investigations in the field of chemical kinetics. It has been speculated that the strong physical-chemical orientation of Wilhelmy's work, the new method of polarimetry, and the fact that Wilhelmy was relatively unknown all led to this situation. Similar laboratory results were published by Jacobus Henricus van 't Hoff and Svante Arrhenius 30 years later, with a much greater impact.
Wilhelmy is also known for the Wilhelmy plate method for measuring surface tensions.
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Notes and references
|This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Ludwig_Wilhelmy". A list of authors is available in Wikipedia.|