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Methoxide is an organic salt, and the smallest alkoxide.
Additional recommended knowledge
Sodium methoxide, also referred to as Sodium methylate, is a white powder when pure. It is used as an initiator of an anionic addition polymerization with ethylene oxide, forming a polyether with high molecular weight. The main application of sodium methoxide today is the use as a catalyst in the production of biodiesel. In this process, vegetable oils or animal fats, which chemically are fatty acid triglycerides, are transesterified with methanol to give fatty acid methyl esters (FAMEs).
Sodium methoxide is produced on an industrial scale and available from a number of chemical companies. The major suppliers today are BASF, Degussa, and Interstate Chemical Company.
NaOH + CH3OH -> H2O + Na+ + CH3O-.
There is an equilibrium between CH3O- and OH-: CH3O- + H2O <--> CH3OH + OH-.
Because the addition of NaOH to CH3OH only results in a small amount of methoxide in solution, referring to this as methoxide is less correct than saying that it is a sodium hydroxide solution in methanol.
This confusion may have arisen since methoxide is a very powerful base that has been used experimentally in several papers and seems to self perpetuate. As methoxide is a powerful base, and base transesterified biodiesel is a common method of production, the use of sodium methoxide can substantially increase yields, however it is very sensitive to water, as little as 1% in a reaction will stop it from working. Water immediately reacts with the sodium methoxide to form caustic soda (NaOH) and methanol. Since water inhibits the base catalyst, this stops transesterification taking place.
Another problem with water is that in the presence of triglycerides (from the biodiesel reaction) sodium / potassium and water when being mixed will undergo saponification (soap formation), another reason why water must be kept out of the system.
Sodium methoxide in methanol is a liquid that kills human nerve cells before any pain can be felt. In the event of contact with methoxide, rinse the contacted area with water, seek medical attention immediately.
Making sodium methoxide is dangerous, involving H2 and lots of heat. In addition, the resultant chemical is highly toxic. For this reason, the safety of the design of your equipment and workspace should be carefully considered before use, and protective clothing and a respirator should be worn during handling. Only as much as is intended to be used immediately should be created.
|This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Methoxide". A list of authors is available in Wikipedia.|