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In geochemistry, paleoclimatology and paleoceanography δ18O is the ratio of stable isotopes 18O:16O. It is commonly used as a measure of the temperature of precipitation, as a measure of groundwater/mineral interactions, as an indicator of processes that show isotopic fractionation, like methanogenesis. In paleosciences, foraminifera and ice core data 18O:16O is used as a proxy for temperature.
Foraminifera shells of calcium carbonate (CaCO3), having oxygen in them, and being found in many common geological features, such as the White Cliffs of Dover that were once at the bottom of the ocean, are most commonly used to do tests on. The ratio of 18O to 16O is used to tell the temperature of the surrounding water of the time solidified, indirectly. The ratio varies slightly depending on the temperature of the surrounding water. Although the change is only about 0.2 parts per thousand decrease for each degree Celsius of temperature increase, this is sufficient to estimate the temperature of the water in which the foraminifera lived in millions of years ago.
δ18O value of the shells depends on the δ18O in the surrounding water, which can be as variable as its temperature. This variability arises because of when water evaporates the lighter molecules of water—those with 16O atoms instead of 18O—tend to evaporate first, because of their lower mass. This makes the water vapor more depleted of 18O than the ocean from which it evaporates. The ocean contains greater amounts of 18O around the subtropics and tropics where there is more evaporation, and lesser amounts of 18O in the mid-latitudes where it rains more.
Similarly, when water vapor condenses, heavier water molecules holding 18O atoms tend to condense and precipitate first. The water vapor gradient, heading from the tropics to the poles gradually becomes more and more depleted of 18O. Snow falling in Canada has much less H218O than rain in Florida.
Changes in climate alter global patterns of evaporation and precipitation therefore change the background δ18O ratio.
|This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Δ18O". A list of authors is available in Wikipedia.|