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1,1'-Bis(diphenylphosphino)ferrocene



1,1'-Bis(diphenylphosphino)ferrocene
Other names 1,1'-Bis(diphenylphosphino)ferrocene, 1,1'-Ferrocenediyl-bis(diphenylphosphine), Dppf, 1,1'-Ferrocenebis(diphenylphosphine)
Identifiers
CAS number 12150-46-8
PubChem 635956
SMILES C1=CC=C(C=C1)P([C-]2C=CC=C2)C3=CC=CC=C3 .C1=CC=C(C=C1)P([C-]2C=CC=C2)C3=CC=CC=C3.[Fe+2]
InChI InChI=1/2C17H14P.Fe/c2*1-3-9-15(10-4-1)18(17- -13-7-8-14-17)16-11-5-2-6-12-16;/h2*1-14H;/q2*-1;+2
Properties
Molecular formula C34H28FeP2
Molar mass 554.391
Melting point

181 - 183 °C

Hazards
Main hazards Toxic
R-phrases R25
S-phrases S28A S45
Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)
Infobox disclaimer and references

1,1'-Bis(diphenylphosphino)ferrocene, commonly abbreviated dppf, is a substituted phosphine commonly used, as are other phosphines, as a ligand in organometallic chemistry. It contains a ferrocene moiety in its backbone, and is closely related to other bridged diphenylphosphines such as 1,1-bis(diphenylphosphino)methane (dppm) and 1,2-bis(diphenylphosphino)ethane (dppe). It is commercially available, and is usually purchased rather than synthesized.

See also
 
This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "1,1'-Bis(diphenylphosphino)ferrocene". A list of authors is available in Wikipedia.
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