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An allene is a hydrocarbon in which one atom of carbon is connected by double bonds with two other atoms of carbon. Allene also is the common name for the parent compound of this series, 1,2-propadiene.
Additional recommended knowledge
The central carbon of allene forms two sigma bonds and two pi bonds. The central carbon is sp-hybridised, and the two terminal carbons are sp2-hybridised. The bond angle formed by the three carbons is 180 degrees, indicating linear geometry for the carbons of allene.
For allenes with four identical substituents, the compound will have a twofold axis of rotation through the center carbon. The axis is inclined at 45° to the CH2 planes on either side of the molecule. The molecule can thus be thought of as a two-bladed propeller. Another twofold axis of rotation passes through the C=C=C bonds, and there is a mirror plane passing through both CH2 planes. Thus this class of molecules will have a D2d point group.
An allene with only two substituents, A and B will be chiral because there will no longer be any mirror planes. Where A has a greater priority than B according to the Cahn-Ingold-Prelog priority rule, the configuration can be determined by considering the top, then the bottom. For the bottom, only the group of higher priority need be considered.
Laboratory methods for the formation of allenes are:
|This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Allene". A list of authors is available in Wikipedia.|