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The ortho-isomer is formed predominantly. However, the para-sulfate is formed in small amounts with certain anilines.
Behrman has shown that the first intermediate in the Boyland-Sims oxidation is the formation of an arylhydroxylamine-O-sulfate (2).zwitterionic intermediate forms both the ortho- and para-amino aryl sulfates (3a and 3b).Rearrangement of this
|This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Boyland-Sims_oxidation". A list of authors is available in Wikipedia.|