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Cacodyl, dicacodyl, tetramethyldiarsine, alkarsine or minor part of the "Cadet's fuming liquid" (after the French chemist Louis Claude Cadet de Gassicourt) (CH3)2As—As(CH3)2 is a poisonous oily liquid with a garlicky odor. Cacodyl undergoes spontaneous combustion in dry air.
Additional recommended knowledge
Cacodyl oxide is prepeared by the reaction of potassium acetate with arsenic trioxide.
4KCH3COO + As2O3 → As2(CH3)4O + 4K2CO3 + CO2
A subsequent reduction or disproportionation of the substance at the reaction condition is leading to a mixture of several methylated arsenic compounds.
A far better synthesis was developed which started from the dimethyl arsine chloride and dimethyl arsine.
As(CH3)2Cl + As(CH3)2H → As2(CH3)4 + HCl
In Bunsen's words "the smell of this body produces instantaneous tingling of the hands and feet, and even giddiness and insensibility...It is remarkable that when one is exposed to the smell of these compounds the tongue becomes covered with a black coating, even when no further evil effects are noticeable".
Work on cacodyl led Bunsen to the postulation of methyl radicals.
Cacodyl was used to proof the radical theory of Berzelius, which resulted in a wide use of cacodyl in research laboratories. After the radical theory was established the interest in the toxic substance with the literally evil smell decreased. During World War I the use of cacodyl as poison gas was considered, but it was never used in the war. The inorganic chemistry discovered the properties of cacodyl as ligand for transition metals.
|This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Cacodyl". A list of authors is available in Wikipedia.|