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Carothers equationIn step-growth polymerization, the Carothers equation (or Carothers' equation) gives the number-average degree of polymerization, X_{n}, for a given fractional monomer conversion, p. Additional recommended knowledgeThis equation was proposed by Wallace Carothers who invented nylon in 1935. Notes:
A high monomer conversion is required to achieve a high number-average degree of polymerization. For example, a monomer conversion, p, of 98% is required for X_{n} = 50, and p = 99% is required for X_{n} = 100.
Related equationsRelated to the Carothers equation are the following equations: where:
The last equation shows that the maximum value of the PDI is 2, which occurs at a monomer conversion of 100%. In practice the average length of the polymer chain is limited by such things as the purity of the reactants, the absence of any side reactions (i.e. high yield), and the viscosity of the medium. |
This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Carothers_equation". A list of authors is available in Wikipedia. |