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Fenton's reagent is a solution of hydrogen peroxide and an iron catalyst that is used to oxidize contaminants or waste waters. Fenton's reagent can be used to destroy organic compounds such as trichloroethylene (TCE) and tetrachloroethylene (PCE).
Additional recommended knowledge
It was developed in the 1890s by Henry John Horstman Fenton.
Ferrous Iron(II) is oxidized by hydrogen peroxide to ferric iron(III), a hydroxyl radical and a hydroxyl anion. Iron(III) is then reduced back to iron(II), a peroxide radical and a proton by the same hydrogen peroxide (disproportionation).
(1) Fe2+ + H2O2 → Fe3+ + OH· + OH−
(2) Fe3+ + H2O2 → Fe2+ + OOH· + H+
In the net reaction the presence of iron is truly catalytic and two molecules of hydrogen peroxide are converted into two hydroxyl radicals and water. The generated radicals then engage in secondary reactions. Iron(II) sulfate is a typical iron compound in Fenton's reagent.
(3) C6H6 + FeSO4 + H2O2 → C6H5OH
A recent hydroxylation example involves the oxidation of barbituric acid to alloxane . Another application of the reagent in organic synthesis is in coupling reactions of alkanes. As an example tert-butanol is dimerized with Fenton's reagent and sulfuric acid to 2,5-dimethyl-2,5-hexanediol.
The mismanagement of iron in cellular systems can lead to the toxic accumulation of iron in organ systems such as the liver and brain. It is believed that this build up of iron eventually leads to the production of free radicals leading to oxidative stress, cellular damage and eventual cellular death via apoptotic signaling.
|This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Fenton's_reagent". A list of authors is available in Wikipedia.|