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Ion cyclotron resonance
Ion cyclotron resonance is a phenomenon related to the movement of ions in a magnetic field. It is used for accelerating ions in a cyclotron, and for measuring the masses of an ionized analyte in mass spectrometry, particularly with Fourier transform ion cyclotron resonance mass spectrometers.
Additional recommended knowledge
Definition of the resonant frequency
An ion in a static and uniform magnetic field will move in a circle due to the Lorentz force. The circular motion may be superimposed with a uniform axial motion, resulting in a helix, or with a uniform motion perpendicular to the field, e.g., in the presence of an electrical or gravitational field, resulting in a cycloid. The angular frequency (ω = 2π f ) of this cyclotron motion for a given magnetic field strength B is given (in SI units) by
where z is the algebric number of positive or negative charges of the ion, e is the elementary charge and m is the mass of the ion.
The formula above means that an electric excitation signal having a frequency f will resonate with ions having a mass-to-charge ratio m/z given by:
|This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Ion_cyclotron_resonance". A list of authors is available in Wikipedia.|