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The Kulinkovich reaction describes the organic synthesis of cyclopropanols via reaction of esters with dialkyldialkoxytitan reagents, generated in situ from Grignard reagents bearing hydrogen in beta-position and titanium(IV) alkoxides. Reaction was found by Kulinkovich and coworkers in 1989. Titanium reagent could be used catalytically.
Additional recommended knowledge
Titanium catalyst: ClTi(OiPr)3 or Ti(OiPr)4, ClTi(OtBu)3 or Ti(OtBu)4
1. Kulinkovich, O. G.; Sviridov, S. V.; Vasilevskii, D. A.; Pritytskaya, T. S. Zh. Org. Khim. 1989, 25, 2244; Kulinkovich,
O.; Sviridov, S.V.; Vasilevski, D.A. Synthesis, 1991, 234.
|This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Kulinkovich_reaction". A list of authors is available in Wikipedia.|