My watch list
my.chemeurope.com

Mass-to-charge ratio

The mass-to-charge ratio, is a physical quantity that is widely used in the electrodynamics of charged particles, e.g. in electron optics and ion optics. It appears in the scientific fields of lithography, electron microscopy, cathode ray tubes, accelerator physics, nuclear physics, auger spectroscopy, cosmology and mass spectrometry. The importance of the mass-to-charge ratio, according to classical electrodynamics, is that two particles with the same mass-to-charge ratio move in the same path in a vacuum when subjected to the same electric and magnetic fields.

Origin

When charged particles move in electric and magnetic fields the following two laws apply: $\mathbf{F} = q (\mathbf{E} + \mathbf{v} \times \mathbf{B}),$ (Lorentz force law) $\mathbf{F}=m\mathbf{a}$ (Newton's second law of motion)

where F is the force applied to the ion, m is the mass of the ion, a is the acceleration, q is the ionic charge, E is the electric field, and v x B is the vector cross product of the ion velocity and the magnetic field

Using Newton's third law of motion yields: $(m/q)\mathbf{a} = \mathbf{E}+ \mathbf{v} \times \mathbf{B}$

This differential equation is the classic equation of motion of charged particles in vacuum. Together with the particles initial conditions it determines the particle's motion in space and time. It immediately reveals that two particles with the same m/q behave the same. This is why the mass-to-charge ratio is an important physical quantity in those scientific fields where charged particles interact with magnetic (B) or electric (E) fields.

Exceptions

There are non-classical effects that derive from quantum mechanics such as the Stern–Gerlach effect that can diverge the path of ions of identical m/q.

Symbols & Units

The official symbol for mass is m. The official symbol for electric charge is Q; however, q is also very common. Charge is a scalar property, meaning it can be either positive (+ symbol) or negative (- symbol). Sometimes, however, the sign of the charge is indicated indirectly. Coulomb is the SI unit of charge, however, other units are not uncommon. (note: The symbol "Q" is also used for other units of measure including flow.)

The SI unit of the physical quantity m / q is kilogram/coulomb.

[m / q] = kg/C

In the field of mass spectrometry the units and notation above are used in the physics of mass spectrometery while the unitless m/z notation is used as the independent variable that the mass spectrometer measures. These notations are closely related through the unified atomic mass unit and the elementary charge. See Mass spectrum.

History

In the 19th century the mass-to-charge ratio of some ions were measured by electrochemical methods. In 1897 the mass-to-charge ratio m / e of the electron was first measured by J.J. Thomson. By doing this he showed that the electron, which was postulated before in order to explain electricity, was in fact a particle with a mass and a charge and that its mass-to-charge ratio was much smaller than that of the hydrogen ion H+. In 1898 Wilhelm Wien separated ions (canal rays) according to their mass-to-charge ratio with an ion optical device with superimposed electric and magnetic fields (Wien filter). In 1901 Walter Kaufman measured the relativistic mass increase of fast electrons. In 1913 J.J. Thomson measured the mass-to-charge ratio of ions with an instrument he called a parabola spectrograph. Today, an instrument that measures the mass-to-charge ratio of charged particles is called mass spectrometer.

Books
• Electron and Ion Optics by Miklos Szilagyi, Plenum Press, ISBN 0-306-42717-6.
• Introduction into optics of charged particles by J. Grosser, Teubner, ISBN 3-519-03050-0.
• Applied charged particle optics, edited by A. Septier, Academic Press, ISBN 0-12-014574-X.
Web sites
• BIPM SI brochure
• IUPAC green book on Quantities, Units and Symbols in Physical Chemistry
• Chapter 12: Mass Spectrometry in the IUPAC orange book

References and notes

1. ^ lemoyne.edu
2. ^ lemoyne.edu
• NIST on units and manuscript check list
• Physics Today's instructions on quantities and units
• International Vocabulary of Basic Terms in Metrology (Second edition 1993: ISBN 92-67-01075-1); a guide with contributions of the following organizations: IUPAP, IUPAC, ISO, OIML, IEC, IFCC.
• IUPAP Red Book SUNAMCO 87-1 "Symbols, Units, Nomenclature and Fundamental Constants in Physics" (does not have an online version).
• Symbols Units and Nomenclature in Physics IUPAP-25 IUPAP-25, E.R. Cohen & P. Giacomo, Physics 146A (1987) 1-68.
• AIP style manual