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Stereoselectivity



In chemistry, stereoselectivity is the property of a chemical reaction that yields an unequal mixture of stereoisomers from a single reactant. Stereoselectivity may be partial, where the formation of one stereoisomer is favoured over the other, or it may be total where only one stereoisomer is formed. An example of partial stereoselectivity is dehydrohalogenation of 2-iodo-butane which yields 80% trans-2-butene and 20% cis-2-butene [1].

Additional recommended knowledge


Stereoconvergence can be considered an opposite of stereoselectivity when reaction of two different isomers yield a single isomer.

See also

References

  1. ^ Effects of base strength and size upon in base-promoted elimination reactions Richard A. Bartsch, Gerald M. Pruss, Bruce A. Bushaw, Karl E. Wiegers J. Am. Chem. Soc.; 1973; 95(10); 3405-3407. doi:10.1021/ja00791a067
 
This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Stereoselectivity". A list of authors is available in Wikipedia.
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