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Each of the two isomers of butane give rise to two isomers of the butyl substituent. Thus, n-butane can connect at either the terminal or an internal carbon atoms, giving rise to "n-butyl" and "sec-butyl" substituents.
The second, branched isomer of butane, isobutane can also connect either terminal methyl or internal carbon atoms, giving rise to "isobutyl" and "tertiary butyl" substituents, respectively.
Additional recommended knowledge
According to IUPAC nomenclature, "isobutyl", "sec-butyl", and "tert-butyl" are all retained trivial names.
Butyl is the largest substituent for which trivial names are commonly used for all isomers.
The prefixes iso, sec and tert refer to the number of carbons connected to the primary carbon (also known as RI ("R prime"), the carbon that is connected to R). Iso means one, sec- means two and tert- means three.
The following are the four isomers of "butyl acetate":
As the number of carbons in an alkyl chain increases, butyl is the last to be named historically instead of through Greek numbers. The name is derived from butyric acid, a four carbon carboxylic acid found in rancid butter. The name of butyric acid, in turn, comes from Latin butyrum, "butter".
The tert-butyl substituent is very bulky and used in chemistry for kinetic stabilisation together with other bulky groups such as the related trimethylsilyl group. The effect that the t-butyl group exerts on the progress of a chemical reaction is called the tert-butyl effect.
|This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Butyl". A list of authors is available in Wikipedia.|