My watch list
my.chemeurope.com  
Login  

Niobium(V) chloride



Niobium(V) chloride
Systematic name Niobium(V) chloride
Niobium pentachloride
Molecular formula NbCl5
Molar mass 270.17 g/mol
Density 2.75 g/cm3
Solubility (water) Decomposes
Solubility (dimethylformamide) Good
Melting point 204.7 °C
Boiling point 254 °C
CAS number [10026-12-7]
EINECS number 233-059-8
Thermodynamic data
Standard enthalpy
of formation
ΔfH°solid
-797.47 kJ/mol
Standard molar entropy
S°solid
214.05 J.K−1.mol−1
Safety data
EU classification not listed
Flash point non-flammable
RTECS number QU0350000
Related compounds
Related chlorides Vanadium(IV) chloride
Tantalum(V) chloride
Disclaimer and references

Niobium(V) chloride, also known as niobium pentachloride, is a yellow crystalline solid often used as a starting material in niobium chemistry. It is prepared by heating niobium metal in chlorine. It is often contaminated with small amounts of niobium(V) oxychloride, NbOCl3, formed by hydrolysis or from traces of oxygen during the preparation. NbCl5 may be purified by sublimation.

Additional recommended knowledge

Contents

Structure and properties

Niobium(V) chloride forms chloro-bridged dimers in the solid state (see figure). Each niobium centre is six-coordinate, but the octahedral coordination is significantly distorted. The niobium–chlorine bond lengths are 225 pm (terminal) and 256 pm (bridging), while the Nb–Cl–Nb angle at the bridge is 101.3°. The Nb–Nb distance is 395.1 pm, too long for any metal-metal interaction. NbBr5, TaCl5 and TaBr5 are isostructural with NbCl5, but NbI5 and TaI5 have different structures.

Uses

Niobium(V) chloride is used in organic chemistry as a Lewis acid in activating alkenes for the carbonyl-ene reaction and the Diels-Alder reaction. Niobium chloride can also generate N-acyliminium compounds from certain pyrrolidines which are substrates for nucleophiles such as allyltrimethylsilane, indole, or the silyl enol ether of benzophenone[1].

Bibliography

References

  1. ^  Andrade, C. K. Z.; Rocha, R. O.; Russowsky, D.; & Godoy, M. N. (2005). Studies on the Niobium Pentachloride-Mediated Nucleophilic Additions to an Enantiopure Cyclic N-acyliminium Ion Derived from (S)-malic acid. J. Braz. Chem. Soc. 16: 535–539. Online Article (.PDF file)
 
This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Niobium(V)_chloride". A list of authors is available in Wikipedia.
Your browser is not current. Microsoft Internet Explorer 6.0 does not support some functions on Chemie.DE