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Structural characteristics of porphin
Around the perimeter of the macrocycle ring, there is a cyclic chain of sp2 hybridized carbon atoms, all of which are part of a conjugated double bond system, giving the molecule its aromatic character. Resonance structures for porphin can be drawn as shown below here.
The aromatic character of porphin stems both from its conjugation as well as its flat or planar geometry, meaning that all the atoms lie in a single plane. Bonded to the cyclic chain of carbons are four nitrogen atoms facing the center of the molecule, two of which are bonded to hydrogen atoms and the other two nitrogens forming part of the conjugated double bond system.
Complex with metal in the center
If the two nitrogens give up their hydrogens, the four central nitrogen atoms can act as ligands to bond to a metal ion in the center of the molecule. This is often the case with biological porphyrin compounds, especially with an iron atom in the center. When there is no metal ion (or atom) bound to the nitrogens in the center, then the compounds are called free porphin or free porphyrins. If they are bonded to a metal in the center, then they are bound. A porphyrin with an iron atom of the type found in hemoglobin or certain cytochromes is called heme. See the Porphyrin article for further details.
Compounds similar to porphin are the parent compounds for similar ring systems with other central metal atoms in biochemistry. These include chlorin, which has a magnesium atom in several types of chlorophyll; bacteriochlorin, found in bacteriochorophyll; and corrin, which has a cobalt atom in cobalamin or vitamin B12.
|This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Porphin". A list of authors is available in Wikipedia.|