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Siegbahn notation



The Siegbahn notation is used in x-ray spectroscopy to name the spectral lines that are characteristic to elements. It was created by Manne Siegbahn.

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The characteristic lines in x-ray emission spectra correspond to electronic transitions where an electron jumps down to an unfilled level in one of the inner shells of an atom. Such a hole in en inner shell may have been produced by bombardment with electrons in an x-ray tube, by other particles as in PIXE, by other x-rays in x-ray fluorescence or by radioactive decay of the atom's nucleus.

The table below show the correspondence between the name of a few lines and the electronic levels.

Siegbahn notation
Low energy level High energy level Name of the line
K (1S0) L3 (²P3/2) Kα1
L2 (²P1/2) Kα2
M3 (³P3/2) Kβ1
L3 (²P3/2) M5 (³D5/2) Lα1
L2 (²P1/2) M4 (³D3/2) Lβ1
M5 (³D5/2) N7 (5P3/2) Mα1

This notation is widely used in spectroscopy, but the IUPAC (International union of pure and applied chemistry) recommends another notation.

Correspondence between the IUPAC Siegbahn notations
Siegbahn notation IUPAC notation
Kα1 K-L3
Kα2 K-L2
Kβ1 K-M3
Lα1 L3-M5
Lβ1 L2-M4
Mα1 M5-N7

References

  • Nomenclature system for x-ray spectroscopy (1991) IUPAC.

See also

 
This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Siegbahn_notation". A list of authors is available in Wikipedia.

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