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Erythritol tetranitrate (ETN) is an explosive compound chemically similar to PETN. It is however thought to be 1/3 more sensitive to friction and impact. ETN is not well known, but in recent years has been used by amateur experimenters to replace PETN in improvised detonation cord or in boosters to initiate larger, less sensitive explosive charges. Due to the availability of erythritol as a natural sweetener and its relative ease of production in relation to PETN, ETN is a favoured home made explosive compound to the amateur experimenter.
Like many nitric esters, ETN acts as a vasodilator. Ingesting ETN or prolonged skin contact can lead to absorption and what is known as a nitro headache.
ETN has a relatively high velocity of detonation of 8000-8100 m/sec at a density of 1.6 g/cm3. It is white in color and odorless. ETN is commonly cast into mixtures with other high explosives. It is somewhat sensitive to shock and friction, so care should be taken while handling. ETN dissolves readily in acetone and other ketone solvents though for the purpose of recrystallization, slow cooling of a saturated solution in ethanol from 55 °C gives much better results with purer and better formed crystals.
Much like PETN, ETN is known for having a very long shelf life. Studies that directly observed the crystalline structure saw no signs of decomposition after four years of storage at room temperature.
One quality this explosive has, that PETN does not, is a positive oxygen balance. Having a positive oxygen balance means that ETN possesses more than enough oxygen in its structure to fully oxidize all of its carbon and hydrogen upon detonation. This can be seen in the equation below.
Whereas PETN decomposes to:
Thus for every mole of ETN that decomposes, 1/2 free mole of O2 is released. This could be used to oxidize an added metal dust or an oxygen deficient explosive such as TNT or PETN.
Like other nitrated polyols, ETN is made by nitrating erythritol through the mixing of concentrated sulfuric acid and a nitrate salt. Ammonium nitrate is commonly used for this type of reaction. The erythritol is added to the mixture to begin its nitration. Much better yields can be obtained by using concentrated nitric acid in place of the nitrate salt, in which case the sulfuric acid is used simply to absorb water from the resulting esterification, driving the reaction.
|This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Erythritol_tetranitrate". A list of authors is available in Wikipedia.|