To use all functions of this page, please activate cookies in your browser.
With an accout for my.chemeurope.com you can always see everything at a glance – and you can configure your own website and individual newsletter.
- My watch list
- My saved searches
- My saved topics
- My newsletter
BCS theory (named after its creators, Bardeen, Cooper, and Schrieffer) explains conventional superconductivity, the ability of certain metals at low temperatures to conduct electricity without electrical resistance. BCS theory views superconductivity as a macroscopic quantum mechanical effect. It proposes that electrons with opposite spin can become paired, forming Cooper pairs. Independently and at the same time, this superconductivity phenomenon was explained by Nikolay Bogoliubov by means of the so-called Bogoliubov transformations.
Additional recommended knowledge
In many superconductors, the attractive interaction between electrons (necessary for pairing) is brought about indirectly by the interaction between the electrons and the vibrating crystal lattice (the phonons). Roughly speaking the picture is the following:
An electron moving through a conductor will attract nearby positive charges in the lattice. This deformation of the lattice causes another electron, with opposite "spin", to move into the region of higher positive charge density. The two electrons are then held together with a certain binding energy. If this binding energy is higher than the energy provided by kicks from oscillating atoms in the conductor (which is true at low temperatures), then the electron pair will stick together and resist all kicks, thus not experiencing resistance.
BCS theory was developed in 1957 by John Bardeen, Leon Cooper, and Robert Schrieffer and they received the Nobel Prize in Physics in 1972 for this theory.
In 1986, "high-temperature superconductivity" was discovered (i.e. superconductivity at temperatures considerably above the previous limit of about 30 K; up to about 130 K). It is believed that at these temperatures other effects are at play; these effects are not yet fully understood. (It is possible that these unknown effects also control superconductivity even at low temperatures for some materials).
BCS Theory starts from the assumption that there is some attraction between electrons, which can overcome the Coulomb repulsion. In most materials (in low temperature superconductors), this attraction is brought about indirectly by the coupling of electrons to the crystal lattice (as explained above). However, the results of BCS theory do not depend on the origin of the attractive interaction. The original results of BCS (discussed below) described an "s-wave" superconducting state, which is the rule among low-temperature superconductors but is not realized in many "unconventional superconductors", such as the "d-wave" high-temperature superconductors. Extensions of BCS theory exist to describe these other cases, although they are insufficient to completely describe the observed features of high-temperature superconductivity.
BCS were able to give an approximation for the quantum-mechanical state of the system of (attractively interacting) electrons inside the metal. This state is now known as the "BCS state".In the normal state of a metal, electrons move independently, whereas in the BCS state they are bound into "Cooper pairs" by the attractive interaction.
BCS have derived several important theoretical predictions that are independent of the details of the interaction, since the quantitative predictions mentioned below hold for any sufficiently weak attraction between the electrons and this last condition is fulfilled for many low temperature superconductors - the so-called "weak-coupling case". These have been confirmed in numerous experiments:
kBTc = 1.14EDexp( − 1 / N(0)V)
The BCS Papers:
L. N. Cooper, "Bound Electron Pairs in a Degenerate Fermi Gas", Phys. Rev 104, 1189 - 1190 (1956).
J. Bardeen, L. N. Cooper, and J. R. Schrieffer, "Microscopic Theory of Superconductivity", Phys. Rev. 106, 162 - 164 (1957).
J. Bardeen, L. N. Cooper, and J. R. Schrieffer, "Theory of Superconductivity", Phys. Rev. 108, 1175 (1957).
|This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "BCS_theory". A list of authors is available in Wikipedia.|