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The term comes from the Greek eutektos, meaning 'easily melted.'
The equilibrium phase diagram at the right displays a simple binary system composed of two components, A and B, which has a eutectic point. The phase diagram plots relative concentrations of A and B along the horizontal axis, and temperature along the vertical axis. The eutectic point is the point at which the liquid phase L borders directly on the solid phase α + β (a homogeneous composed of both A and B), representing the minimum melting temperature of any possible alloy of A and B.
Not all binary system alloys have a eutectic point: those that form a solid solution at all concentrations, such as the gold-silver system, have no eutectic. An alloy system that has a eutectic is often referred to as a eutectic system, or eutectic alloy.
Solid products of a eutectic reaction can often be identified by their lamellar structure, as opposed to the dendritic structures commonly seen in non-eutectic solidification. The same conditions that force the material to form lamellae can instead form an amorphous solid if pushed to an extreme.
Additional recommended knowledge
The term is often used in metallurgy to describe the alloy of two or more component materials having the relative concentrations specified at the eutectic point. When a non-eutectic alloy freezes, one component of the alloy crystallizes at one temperature and the other at a different temperature. With a eutectic alloy, the mixture freezes as one at a single temperature. A eutectic alloy therefore has a sharp melting point, and a non-eutectic alloy exhibits a plastic melting range. The phase transformations that occur while freezing a given alloy can be understood using the phase diagram by drawing a vertical line from the liquid phase to the solid phase on a phase diagram; each point along the line describes the composition at a given temperature.
Some uses include:
Other eutectic mixtures
Sodium chloride and water form a eutectic mixture. It has a eutectic point of −21.2 C and 23.3% salt by weight. The eutectic nature of salt and water is exploited when salt is spread on roads to aid snow removal, or mixed with ice to produce low temperatures (for example, in traditional ice cream making).
Some inks are eutectic mixtures, allowing inkjet printers to operate at lower temperatures.
Other critical points
When the solution above the transformation point is solid, rather than liquid, an analogous eutectoid transformation can occur. For instance, in the iron-carbon system, the austenite phase can undergo a eutectoid transformation to produce ferrite and cementite (iron carbide), often in lamellar structures such as pearlite and bainite. This eutectoid point occurs at 727°C (1340.6 ºF) and about 0.8% carbon; alloys of nearly this composition are called high-carbon steel, while those which have less carbon are termed mild steel. The process analogous to glass formation in this system is the martensitic transformation.
Peritectic transformations are also similar to eutectic reactions. Here, a liquid and solid phase of fixed proportions react at a fixed temperature to yield a single solid phase. Since the solid product forms at the interface between the two reactants, it can form a diffusion barrier and generally causes such reactions to proceed much more slowly than eutectic or eutectoid transformations. Because of this, when a peritectic composition solidifies it does not show the lamellar structure that you find with eutectic freezing.
Such a transformation exists in the iron-carbon system, as seen near the upper-left corner of the figure. It resembles an inverted eutectic, with the δ phase combining with the liquid to produce pure austenite at 1495 °C and 0.17 mass percent carbon.
|This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Eutectic_point". A list of authors is available in Wikipedia.|