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Sal ammoniac



Sal ammoniac
CategoryHalide Group Mineral
Chemical formulaNH4Cl
Identification
Molecular Weight53.49 g/mol
ColorColorless, White,
Crystal habitmassive, Encrustations
Crystal systemIsometric
Twinningon the {111}
Cleavageimperfect on the {111}
FractureConcoidal
TenacitySectile
Mohs Scale hardness1-2
LusterVitreous
Optical PropertiesIsotropic
Birefringenceweak after deformation
StreakWhite
Density1.535 g/cm3
Solubilityin water
DiaphaneityTransparent
References[1] [2] [3]

Sal ammoniac is a rare mineral composed of ammonium chloride, NH4Cl. It forms colorless to white to yellow brown crystals in the isometric-hexoctahedral class. It has very poor cleavage and a brittle to conchoidal fracture. It is quite soft, with a Mohs hardness of 1.5 to 2, and has a low specific gravity of 1.5. It is water-soluble.

Additional recommended knowledge

It typically forms as encrustations formed by sublimation around volcanic vents. It is found around volcanic fumaroles, guano deposits and burning coal seams. Associated minerals include sodium alum, native sulfur and other fumarole minerals. Notable occurrences include Tadzhikistan; Mt. Vesuvius, Italy; and Parícutin, Michoacan, Mexico.

Sal ammoniac is also the archaic name for the chemical compound ammonium chloride; from Greek, άλς άμμωνιακός hals ammoniakos, salt of Ammon, because of its early manufacture in Egypt.

It is commonly used as a flux in the soldering of stained-glass windows. In both jewelery-making and the refining of precious metals, potassium carbonate (cream of tartar) is added to gold and silver in a borax-coated crucible to purify iron or steel filings that may have contaminated the scrap. It is then air-cooled and remelted with a one-to-one mixture of powdered charcoal and sal ammoniac to yield a sturdy ingot of the respective metal or alloy in the case of sterling silver (0.75% copper) or karated gold. Anything other than 24-karat gold has silver and copper added. Usually the addition of silica, zinc, and deoxidants in very small amounts relative to the pennyweight (dwt.) of gold are processed into gold from as low as 8-karat to as high as 23.5-karat gold. This is added to prevent porosity or cracking while milling the ingot further into wire, sheet, or tubing. Without those additives an otherwise poor-quality ingot will result in open crucible melting with a hand torch or blowpipe and flame, as was done before electric melting furnaces were invented for use in the precious metals industry. These practices are still used by metalsmiths and jewelers today.

Sal ammoniac has also been used in the past in bakery products to give cookies a very crisp texture, although that application is rapidly dying due to the general disuse of it as an ingredient. However, in some areas of Europe, particularly Scandinavia, it is still widely used in the production of salty licorice candy known as Salmiak. The term sal ammoniac has largely fallen out of general use in the 20th century.

References

  1. ^ http://www.mindat.org/min-3507.html
  2. ^ http://webmineral.com/data/Sal-ammoniac.shtml
  3. ^ http://rruff.geo.arizona.edu/doclib/hom/salammoniac.pdf
  • Webmineral data
  • Mindat with location data
  • Mineral galleries
 
This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Sal_ammoniac". A list of authors is available in Wikipedia.
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