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Wüstite (FeO) is a mineral form of iron(II) oxide found with meteorites and native iron. It has a gray color with a greenish tint in reflected light. Wüstite crystallizes in the isometric - hexoctahedral crystal system in opaque to translucent metallic grains. It has a Mohs hardness of 5 to 5.5 and a specific gravity of 5.88. Wüstite is a typical example of a non-stoichiometric compound.
In addition to the type locality in Germany, it has been reported from Disko Island, Greenland; the Jharia coalfield, Bihar, India and as inclusions in diamonds in a number of kimberlite pipes. It also is reported from deep sea manganese nodules.
Its presence indicates a highly reducing environment.
Additional recommended knowledge
Wüstite Redox Buffer
Wüstite, in geochemistry, defines a redox buffer of oxidation within rocks at which point the rock is so reduced that Fe3+ and thus hematite is absent.
As the redox state of a rock is further reduced, magnetite is converted to wüstite. This occurs by conversion of the Fe3+ ions in magnetite to Fe2+ ions. An example reaction is presented below;
magnetite + graphite/diamond --> wüstite + carbon monoxide
The formula for magnetite is more accurately written as FeO.Fe2O3 than as Fe3O4. Magnetite is one part wüstite (FeO) and one part hematite (Fe2O3), rather than a solid solution of wüstite and hematite. The magnetite is termed a redox buffer because until all Fe3+ magnetite is converted to Fe2+ the oxide mineral assemblage of iron remains wüstite-magnetite, and furthermore the redox state of the rock remains at the same level of oxygen fugacity. This is similar to buffering in the H+/OH- acid-base system of water.
Once the Fe3+ is consumed, then oxygen must be stripped from the system to further reduce it and wüstite is converted to native iron. The oxide mineral equilibrium assemblage of the rock becomes wüstite-magnetite-iron.
In nature, the only natural systems which are chemically reduced enough to even attain a wüstite-magnetite composition are rare, including carbonate-rich skarns, meteorites and perhaps the mantle where reduced carbon is present, exemplified by the presence of diamond and/or graphite.
Effects upon silicate minerals
Main article: Normative mineralogy
The ratio of Fe2+ to Fe3+ within a rock determines, in part, the silicate mineral assemblage of the rock. Within a rock of a given chemical composition, iron enters minerals based on the bulk chemical composition and the mineral phases which are stable at that temperature and pressure. Iron may only enter minerals such as pyroxene and olivine if it is present as Fe2+; Fe3+ cannot enter the lattice of fayalite olivine and thus for every two Fe3+ ions, one Fe2+ is used and one molecule of magnetite is created.
In chemically reduced rocks, magnetite may be absent due to the propensity of iron to enter olivine, and wüstite may only be present if there is an excess of iron above what can be used by silica. Thus, wüstite may only be found in silica-undersaturated compositions which are also heavily chemically reduced, satisfying both the need to remove all Fe3+ and to maintain iron outside of silicate minerals.
In nature, carbonate rocks, potentially carbonatite, kimberlites, carbonate-bearing melilitic rocks and other rare alkaline rocks may satisfy these criteria. However, wüstite is not reported in most of these rocks in nature, potentially because the redox state necessary to drive magnetite to wüstite is so rare.
Oxidation of wüstite forms goethite-limonite.
Zinc, aluminium and other transition metals may substitute for Fe in wüstite.
|This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Wüstite". A list of authors is available in Wikipedia.|