Metal Organic Frameworks

News Metal Organic Frameworks

• Trapping of Acetylene
  

  Ethylene, a key feedstock in the chemical industry, often includes traces of acetylene contaminants, which need to be removed. In the journal Angewandte Chemie, researchers describe a robust and regenerable porous metal–organic framework that captures acetylene with extraordinary efficiency and sele more

• Programmable synthetic materials
  

  In DNA, information is stored in the sequence of chemical building blocks; in computers, information consists of sequences of zeros and ones. Researchers want to transfer this concept to artificial molecules. Artificial molecules could one day form the information unit of a new type of computer or b more

• Tandem catalytic system efficiently converts carbon dioxide to methanol
  

  Converting carbon dioxide to methanol, a potentially renewable alternative fuel, offers an opportunity to simultaneously form an alternative fuel and cut down on carbon dioxide emissions. Inspired by naturally occurring processes, a team of Boston College chemists used a multi-catalyst system to con more

Infographics Metal Organic Frameworks

Capturing Neon in a Metal-Organic Framework

Here’s the latest graphic from Chemunicate (the Compound Interest side project that works with chemistry researchers and institutions to highlight their research in graphical form). This graphic is a collaboration with the Cambridge Crystallographic Data Centre (CCDC) and looks at their recent resea more

Publications Metal Organic Frameworks

• Direct water-based synthesis and characterization of new Zr/Hf-MOFs with dodecanuclear clusters as IBU

  Two new metal-organic framework compounds of composition [M12(μ3-O)8(μ3-OH)8(μ-OH)6(OH)6(H2O)6(APDC)6], with M = Zr and Hf denoted as M-CAU-39, containing the azopyridinedicarboxylate ion (APDC2-) as a new linker, were obtained by a water based synthesis. The crystal structure was determined from po more

• Microwave-assisted dry-gel conversion - a new sustainable route for the rapid synthesis of metal-organic frameworks with solvent re-use

  Microwave-assisted dry-gel conversion (MW-DGC) combines advantages of concentrated reactants in DGC with fast heating by microwave irradiation. This novel combination allows to drastically decrease the amount of solvent needed for synthesis and reaction times with energy needed. Further, MW-DGC allo more

• Hydrogen-bonded organic frameworks: design, structures and potential applications

  Hydrogen-bonded organic frameworks (HOFs), a new type of porous material following the metal-organic frameworks (MOFs), covalent organic frameworks (COFs), etc., have emerged as one of the promising candidates in diverse potential applications. In this highlight, we summarize the key progress of the more