A 'recipe book' that creates color centers in silicon carbide crystals
Different temperature and proton dosages for the generation of defects
Silicon carbide (SiC), a material known for its toughness with applications from abrasives to car brakes, to high-temperature power electronics, has enjoyed renewed interest for its potential in quantum technology. Its ability to house optically excitable defects, called color centers, has made it a strong candidate material to become the building block of quantum computing.
Green SiC substrate at the bottom with the graphene layer on top irradiated by protons, generating a luminescent defect in the SiC crystal.
Maximilian Rühl
Now, a group of researchers has created a list of "recipes" physicists can use to create specific types of defects with desired optical properties in SiC. In one of the first attempts to systematically explore color centers, the group used proton irradiation techniques to create the color centers in silicon carbide. They adjusted proton dose and temperature to find the right conditions that reliably produce the desired type of color center.
Atomic defects in the lattice of SiC crystals create color centers that can emit photons with unique spectral signatures. While some materials considered for quantum computing require cryogenically low temperatures, color centers in SiC can emit at room temperature. As the push to create increasingly smaller devices continues into atom-scale sensors and single-photon emitters, the ability to take advantage of existing SiC integrated circuit technology makes the material a standout candidate.
To create the defects, Michael Krieger and his colleagues bombarded SiC samples with protons. The team then let the SiC go through a heating phase called annealing. "We're doing a lot of damage to these crystals," Krieger said. "However, during annealing, the crystal structure recovers, but defects are also formed -- some of them are the desired color centers."
To ensure that their recipes are compatible with usual semiconductor technology, the group opted to use proton irradiation. Moreover, this approach doesn't require electron accelerators or nuclear reactors like other techniques used to create color centers.
The data from using different doses and annealing temperatures showed that producing defects in SiC follows a pattern. Initially protons generate predominantly silicon vacancies in the crystal, then those vacancies sequentially transform into other defect complexes.
Studying the defects' low-temperature photoluminescence spectra led the team to discover three previously unreported signatures. The three temperature-stable (TS) lines were shown to correlate with proton dose and annealing temperature.
Krieger said these TS lines have exciting properties and further research is already going on as the group hopes to utilize and control those defects for use in SiC-based quantum technology devices.
Original publication
Other news from the department science
Get the chemical industry in your inbox
From now on, don't miss a thing: Our newsletter for the chemical industry, analytics, lab technology and process engineering brings you up to date every Tuesday and Thursday. The latest industry news, product highlights and innovations - compact and easy to understand in your inbox. Researched by us so you don't have to.
Most read news
More news from our other portals
See the theme worlds for related content
Topic world Sensor technology
Sensor technology has revolutionized the chemical industry by providing accurate, timely and reliable data across a wide range of processes. From monitoring critical parameters in production lines to early detection of potential malfunctions or hazards, sensors are the silent sentinels that ensure quality, efficiency and safety.
Topic world Sensor technology
Sensor technology has revolutionized the chemical industry by providing accurate, timely and reliable data across a wide range of processes. From monitoring critical parameters in production lines to early detection of potential malfunctions or hazards, sensors are the silent sentinels that ensure quality, efficiency and safety.
