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Rutherfordium



104 lawrenciumrutherfordiumdubnium
Hf

Rf

(Upq)
General
Name, Symbol, Number rutherfordium, Rf, 104
Chemical series transition metals
Group, Period, Block 4, 7, d
Standard atomic weight (265)  g·mol−1
Electron configuration probably [Rn] 5f14 6d2 7s2
Electrons per shell 2, 8, 18, 32, 32, 10, 2
Physical properties
Phase presumably a solid
Density (near r.t.) 23 (est.)  g·cm−3
Atomic properties
Crystal structure cubic body centered
Oxidation states 3, 4
Ionization energies 1st: 580 kJ/mol
Atomic radius (calc.) 150  pm
Covalent radius 74 (calc.)  pm
Miscellaneous
CAS registry number 53850-36-5
Selected isotopes
Main article: Isotopes of rutherfordium
iso NA half-life DM DE (MeV) DP
265Rf syn 13 h
References

Rutherfordium (pronounced /ˌrʌðɚˈfɔrdiəm/), also called eka-hafnium, is a chemical element in the periodic table that has the symbol Rf and atomic number 104. This is a highly radioactive synthetic element whose most stable isotope is 265Rf with a half-life of approximately 13 hours.

Additional recommended knowledge

This element therefore has no applications and little is known about it. Rutherfordium is the first transactinide element and it is predicted to have chemical properties similar to hafnium.

History

Rutherfordium was reportedly first synthesized in 1964 at the Joint Nuclear Research Institute at Dubna (U.S.S.R.). Researchers there bombarded 242Pu with accelerated 113 to 115 MeV 22Ne ions and claimed that they detected nuclear fission tracks in a special type of glass with a microscope which indicated the presence of a new element.

In 1969 researchers at the University of California, Berkeley synthesized the element by subjecting 249Cf and 12C to high energy collisions. The UC group also stated that they could not reproduce the earlier synthesis by Soviet scientists.

This resulted in an element naming controversy; since the Soviets claimed that it was first detected in Dubna, dubnium (Db) was suggested, as was kurchatovium (pronounced /ˌkɝtʃəˈtoʊviəm/, symbol Ku) for element 104, in honor of Igor Vasilevich Kurchatov (1903-1960), former head of Soviet nuclear research. The Americans, however, proposed rutherfordium (Rf) for the new element to honor Ernest Rutherford, who is known as the "father" of nuclear physics. The International Union of Pure and Applied Chemistry (IUPAC) adopted unnilquadium (/ˌjuːnɪlˈkwɒdiəm/, symbol Unq) as a temporary, systematic element name, derived from the Latin names for digits 1, 0, and 4. However in 1997 they resolved the dispute and adopted the current name. (Element 105 was named Dubnium, instead.)[1]

References

  1. ^ Michael Freemantle (2003). Rutherfordium. Chemical & Engineering News.
  • Los Alamos National Laboratory Rutherford
 
This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Rutherfordium". A list of authors is available in Wikipedia.
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