To use all functions of this page, please activate cookies in your browser.
With an accout for my.chemeurope.com you can always see everything at a glance – and you can configure your own website and individual newsletter.
- My watch list
- My saved searches
- My saved topics
- My newsletter
A spectral line is a dark or bright line in an otherwise uniform and continuous spectrum, resulting from an excess or deficiency of photons in a narrow frequency range, compared with the nearby frequencies.
Spectral lines are the result of interaction between a quantum system (usually atoms, but sometimes molecules or atomic nuclei) and single photons. When a photon has exactly the right energy to allow a change in the energy state of the system (in the case of an atom this is usually an electron changing orbitals), the photon is absorbed. Then it will be spontaneously re-emitted, either in the same frequency as the original or in a cascade, where the sum of the energies of the photons emitted will be the same as the energy of the one absorbed. The direction of the new photons will not be related to the direction of travel of the original photon.
Depending on the geometry of the gas, the photon source and the observer, either an emission line or an absorption line will be produced. If the gas is between the photon source and the observer, a decrease in the intensity of light in the frequency of the incident photon will be seen, as the reemitted photons will mostly be in directions different from the original one. This will be an absorption line. If the observer sees the gas, but not the original photon source, then the observer will see only the photons reemitted in a narrow frequency range. This will be an emission line.
Absorption and emission lines are highly atom-specific, and can be used to easily identify the chemical composition of any medium capable of letting light pass through it (typically gas is used). Several elements were discovered by spectroscopic means -- helium, thallium, cerium, etc. Spectral lines also depend on the physical conditions of the gas, so they are widely used to determine the chemical composition of stars and other celestial bodies that cannot be analyzed by other means, as well as their physical conditions.
Isomer shift is the displacement of an absorption line due to the absorbing nuclei having different s-electron densities from that of the emitting nuclei.
Mechanisms other than atom-photon interaction can produce spectral lines. Depending on the exact physical interaction (with molecules, single particles, etc.) the frequency of the involved photons will vary widely, and lines can be observed across all the electromagnetic spectrum, from radio waves to gamma rays.
Spectral line broadening and shift
A spectral line extends over a range of frequencies, not a single frequency (i.e., it has a nonzero linewidth). In addition its center may be shifted from its nominal central wavelength. There are several reasons for this broadening and shift. These reasons may be divided into two broad categories - broadening due to local conditions and broadening due to extended conditions. Broadening due to local conditions is due to effects which hold in a small region around the emitting element, usually small enough to assure local thermodynamic equilibrium. Broadening due to extended conditions may result from changes to the spectral distribution of the radiation as it traverses its path to the observer. It also may result from the combining of radiation from a number of regions which are far from each other.
Broadening due to local effects
Broadening due to non-local effects
Certain types of broadening are the result of conditions over a large region of space rather than simply upon conditions that are local to the emitting particle.
Any of these mechanisms can act in isolation or in combination. Assuming each effect is independent of the other, the combined line profile will be the convolution of the line profiles of each mechanism. For example, a combination of thermal Doppler broadening and impact pressure broadening will yield a Voigt profile.
|This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Spectral_line". A list of authors is available in Wikipedia.|