My watch list
my.chemeurope.com

# Bose–Einstein condensate

A Bose–Einstein condensate (BEC) is a state of matter formed by a system of bosons confined in an external potential and cooled to temperatures very near to absolute zero (0 kelvin or -273.15 °C). Under such supercooled conditions, a large fraction of the atoms collapse into the lowest quantum state of the external potential, at which point quantum effects become apparent on a macroscopic scale.

This state of matter was first predicted as a consequence of quantum mechanics by Albert Einstein, building upon the work of Satyendra Nath Bose in 1925, hence the name. Seventy years later, the first such condensate was produced by Eric Cornell and Carl Wieman in 1995 at the University of Colorado at Boulder NIST-JILA lab, using a gas of rubidium atoms cooled to 170 nanokelvin (nK). Eric Cornell, Carl Wieman and Wolfgang Ketterle at MIT were awarded the 2001 Nobel Prize in Physics in Stockholm, Sweden.

## Introduction

"Condensates" are extremely low-temperature fluids with properties that are currently not completely understood, such as spontaneously flowing out of their container. The effect is the consequence of quantum mechanics, which states that systems can only acquire energy in discrete steps. If a system is at such a low temperature that it is in the lowest energy state, it is no longer possible for it to reduce its energy, not even by friction. Without friction, the fluid will easily overcome gravity because of adhesion between the fluid and the container wall, and it will take up the most favorable position, all around the container.

Bose-Einstein condensation is an exotic quantum phenomenon that was observed in dilute atomic gases for the first time in 1995, and is now the subject of intense theoretical and experimental study.

## Theory

The slowing of atoms by use of cooling apparatuses produces a singular quantum state known as a Bose condensate or Bose–Einstein condensate. This phenomenon was predicted in 1925 by generalizing Satyendra Nath Bose's work on the statistical mechanics of (massless) photons to (massive) atoms. (The Einstein manuscript, believed to be lost, was found in a library at Leiden University in 2005.[1]) The result of the efforts of Bose and Einstein is the concept of a Bose gas, governed by the Bose–Einstein statistics, which describes the statistical distribution of identical particles with integer spin, now known as bosons. Bosonic particles, which include the photon as well as atoms such as helium-4, are allowed to share quantum states with each other. Einstein demonstrated that cooling bosonic atoms to a very low temperature would cause them to fall (or "condense") into the lowest accessible quantum state, resulting in a new form of matter.

This transition occurs below a critical temperature, which for a uniform three-dimensional gas consisting of non-interacting particles with no apparent internal degrees of freedom is given by:

$T_c=\left(\frac{n}{\zeta(3/2)}\right)^{2/3}\frac{h^2}{2\pi m k_B}$

where:

 $\,T_c$ is the critical temperature, $\,n$ is the particle density, $\,m$ is the mass per boson, $\,h$ is Planck's constant, $\,k_B$ is the Boltzmann constant, and $\,\zeta$ is the Riemann zeta function; $\,\zeta(3/2)\approx 2.6124.$ (sequence A078434 in OEIS)

### Einstein's Argument

Consider a collection of N noninteracting particles which can each be in one of two quantum states, |0> and |1>. If the two states are equal in energy, each different configuration is equally likely.

If we can tell which particle is which, there are 2N different configurations, since each particle can be in |0> or |1> independently. In almost all the configurations, about half the particles are in |0> and the other half in |1>. The balance is a statistical effect--- the number of configurations is largest when the particles are divided equally.

If the particles are indistinguishable, however, there are only N+1 different configurations. If there are K particles in state |0>, there are N-K particles in state |1>. Whether any particular particle is in state |0> or in state |1> can't be determined, so each value of K determines a unique quantum state for the whole system. If all these states are equally likely, there is no statistical spreading out--- it is just as likely for all the particles to sit in |0> as for the particles to be split half and half.

Supposing now that the energy of state |1> is slightly greater than the energy of state |0> by an amount E. At temperature T, a particle will have a lesser probability to be in state |1> by exp(-E/T). In the distinguishable case, the particle distribution will be biased slightly towards state |0> and the distribution will be slightly different from half and half. But in the indistinguishable case, since there is no statistical pressure toward equal numbers, the most likely outcome is that all the particles will collapse into state |0>.

In the distinguishable case, for large N, the fraction in state |0> can be computed. It is the same as coin flipping with a coin which has probability p=exp(-E/T) to land tails. The fraction of heads is 1/(1+p), which is a smooth function of p, of the energy.

In the indistinguishable case, each value of K is a single state, which has its own separate Boltzmann probability. So the probability distribution is exponential:

$\, P(K)= C e^{-KE/T} = C p^K$

For large N, the normalization constant C is (1-p). The expected total number of particles which are not in the lowest energy state, in the limit that $\scriptstyle N\rightarrow \infty$, is equal to $\scriptstyle \sum_{n>0} C n p^n=p/1-p$. It doesn't grow when N is large, it just approaches a constant. This will be a negligible fraction of the total number of particles. So a collection of enough bose particles in thermal equilbrium will mostly be in the ground state, with only a few in any excited state, no matter how small the energy difference.

Consider now a gas of particles, which can be in different momentum states labelled |k>. If the number of particles is less than the number of thermally accessible states, for high temperatures and low densities, the particles will all be in different states. In this limit the gas is classical. As the density increases or the temperature decreases, the number of accessible states per particle becomes smaller, and at some point more particles will be forced into a single state than the maximum allowed for that state by statistical weighting. From this point on, any extra particle added will go into the ground state.

To calculate the transition temperature at any density, integrate over all momentum states the expression for maximum number of excited particles p/1-p:

$\, N = V \int {d^3k \over (2\pi)^3} {p(k)\over 1-p(k)} = V \int {d^3k \over (2\pi)^3} {1 \over e^{k^2\over 2mT}-1}$
$\, p(k)= e^{-k^2\over 2mT}$

The integral, when evaluated, with the factors of kB and $\scriptstyle \hbar$ restored by dimensional analysis, gives the critical temperature formula of the preceding section. It can be seen that this integral defines the critical temperature and particle number corresponding to the conditions of zero chemical potential (μ = 0 in the Bose–Einstein statistics distribution).

### The Gross-Pitaevskii equation

The state of the BEC can be described by the wavefunction of the condensate $\psi(\vec{r})$. For a system of this nature, $|\psi(\vec{r})|^2$ is interpreted as the particle density, so the total number of atoms is $N=\int d\vec{r} |\psi(\vec{r})|^2$

Provided essentially all atoms are in the condensate (that is, have condensed to the ground state), and treating the bosons using Mean field theory, the energy (E) associated with the state $\psi(\vec{r})$ is:

$E=\int d\vec{r}\left[\frac{\hbar^2}{2m}|\nabla\psi(\vec{r})|^2+V(\vec{r})|\psi(\vec{r})|^2+\frac{1}{2}U_0|\psi(\vec{r})|^4\right]$

Minimising this energy with respect to infinitesimal variations in $\psi(\vec{r})$, and holding the number of atoms constant, yields the Gross-Pitaevski equation (GPE) (also a non-linear Schrödinger equation):

$i\hbar\frac{\partial \psi(\vec{r})}{\partial t} = \left(-\frac{\hbar^2\nabla^2}{2m}+V(\vec{r})+U_0|\psi(\vec{r})|^2\right)\psi(\vec{r})$

where:

 $\,m$ is the mass of the bosons, $\,V(\vec{r})$ is the external potential, $\,U_0$ is representative of the inter-particle interactions.

The GPE provides a good description the behavior of the BEC's and is the approach often applied to their theoretical analysis.

## Discovery

In 1938, Pyotr Kapitsa, John Allen and Don Misener discovered that helium-4 became a new kind of fluid, now known as a superfluid, at temperatures below 2.17 Kelvin (lambda point). Superfluid helium has many unusual properties, including zero viscosity (the ability to flow without dissipating energy) and the existence of quantized vortices. It was quickly realized that the superfluidity was due to Bose–Einstein condensation of the helium-4 atoms, which are bosons. In fact, many of the properties of superfluid helium also appear in the gaseous Bose–Einstein condensates created by Cornell, Wieman and Ketterle (see below). Superfluid helium-4 is a liquid rather than a gas, which means that the interactions between the atoms are relatively strong; the original theory of Bose–Einstein condensation must be heavily modified in order to describe it. Bose–Einstein condensation remains, however, fundamental to the superfluid properties of helium-4.

The first "pure" Bose–Einstein condensate was created by Eric Cornell, Carl Wieman, and co-workers at JILA on June 5, 1995. They did this by cooling a dilute vapor consisting of approximately 2000 rubidium-87 atoms to below 170 nK using a combination of laser cooling (a technique that won its inventors Steven Chu, Claude Cohen-Tannoudji, and William D. Phillips the 1997 Nobel Prize in Physics) and magnetic evaporative cooling. About four months later, an independent effort led by Wolfgang Ketterle at MIT created a condensate made of sodium-23. Ketterle's condensate had about a hundred times more atoms, allowing him to obtain several important results such as the observation of quantum mechanical interference between two different condensates. Cornell, Wieman and Ketterle won the 2001 Nobel Prize in Physics for their achievement [1].

The Bose–Einstein condensation also applies to quasiparticles in solids. A magnon in an antiferromagnet carries spin 1 and thus obeys the Bose–Einstein statistics. The density of magnons is controlled by an external magnetic field, which plays the role of the magnon chemical potential. This technique provides access to a wide range of boson densities from the limit of a dilute Bose gas to that of a strongly interacting Bose liquid. A magnetic ordering observed at the point of condensation is the analog of superfluidity. In 1999 Bose condensation of magnons was demonstrated in the antiferromagnet TlCuCl3.[2] The condensation was observed at temperatures as large as 14 K. Such a high transition temperature (relative to that of atomic gases) is due to a greater density achievable with magnons and a smaller mass (roughly equal to the mass of an electron). In 2006, condensation of magnons in ferromagnets was even shown at room temperature, [3], where the authors used pumping techniques.

## Velocity-distribution data graph

In the image accompanying this article, the velocity-distribution data confirms the discovery of the Bose–Einstein condensate out of a gas of rubidium atoms. The false colors indicate the number of atoms at each velocity, with red being the fewest and white being the most. The areas appearing white and light blue are at the lowest velocities. The peak is not infinitely narrow because of the Heisenberg uncertainty principle: since the atoms are trapped in a particular region of space, their velocity distribution necessarily possesses a certain minimum width. This width is given by the curvature of the magnetic trapping potential in the given direction. More tightly confined directions have bigger widths in the ballistic velocity distribution. This anisotropy of the peak on the right is a purely quantum-mechanical effect and does not exist in the thermal distribution on the left. This famous graph served as the cover-design for 1999 textbook Thermal Physics by Ralph Baierlein[4].

## Vortices

As in many other systems, vortices can exist in BECs. These can be created, for example, by 'stirring' the condensate with lasers, or rotating the confining trap. The vortex created will be a quantum vortex. These phenomena are allowed for by the non-linear term in the GPE (the $|\psi(\vec{r})|^2$ term, that is). As the vortices must have quantised angular momentum, the wavefunction will be of the form $\psi(\vec{r})=\phi(\rho,z)e^{i\ell\theta}$ where ρ,z and θ are as in the cylindrical coordinate system, and $\ell$ is the angular number. To determine φ(ρ,z), the energy of $\psi(\vec{r})$ must be minimised, according to the constraint $\psi(\vec{r})=\phi(\rho,z)e^{i\ell\theta}$. This is usually done computationally, however in a uniform medium the analytic form

$\phi=\frac{nx}{\sqrt{2+x^2}}$

where:

 $\,n^2$ is density far from the vortex, $\,x = \frac{\rho}{\ell\xi},$ $\,\xi$ is healing length of the condensate.

demonstrates the correct behavior, and is a good approximation.

A singly-charged vortex ($\ell=1$) is in the ground state, with its energy εv given by

$\epsilon_v=\pi n \frac{\hbar^2}{m}\ln\left(1.464\frac{b}{\xi}\right)$

where:

 $\,b$ is the farthest distance from the vortex considered.

(to obtain an energy which is well defined it is necessary to include this boundary b)

For multiply-charged vortices ($\ell >1$) the energy is approximated by

$\epsilon_v\approx \ell^2\pi n \frac{\hbar^2}{m}\ln\left(\frac{b}{\xi}\right)$

which is greater than that of $\ell$ singly-charged vortices, indicating that these multiply-charged vortices are unstable to decay. Research has, however, indicated they are metastable states, so may have relatively long lifetimes.

## Unusual characteristics

Further experimentation by the JILA team in 2000 uncovered a hitherto unknown property of Bose–Einstein condensates. Cornell, Wieman, and their coworkers originally used rubidium-87, an isotope whose atoms naturally repel each other, making a more stable condensate. The JILA team instrumentation now had better control over the condensate so experimentation was made on naturally attracting atoms of another rubidium isotope, rubidium-85 (having negative atom-atom scattering length). Through a process called Feshbach resonance involving a sweep of the magnetic field causing spin flip collisions, the JILA researchers lowered the characteristic, discrete energies at which the rubidium atoms bond into molecules making their Rb-85 atoms repulsive and creating a stable condensate. The reversible flip from attraction to repulsion stems from quantum interference among condensate atoms which behave as waves.

When the scientists raised the magnetic field strength still further, the condensate suddenly reverted back to attraction, imploded and shrank beyond detection, and then exploded, blowing off about two-thirds of its 10,000 or so atoms. About half of the atoms in the condensate seemed to have disappeared from the experiment altogether, not being seen either in the cold remnant or the expanding gas cloud.[5] Carl Wieman explained that under current atomic theory this characteristic of Bose–Einstein condensate could not be explained because the energy state of an atom near absolute zero should not be enough to cause an implosion; however, subsequent mean-field theories have been proposed to explain it.

Because supernova explosions are implosions, the explosion of a collapsing Bose–Einstein condensate was named "bosenova", a pun on the musical style bossa nova.

The atoms that seem to have disappeared almost certainly still exist in some form, just not in a form that could be detected in that experiment. Two likely possibilities are that they formed molecules consisting of two bonded rubidium atoms, or that they somehow received enough energy to fly away fast enough that they left the observation region before they could be observed.

## Current research

Compared to more commonly-encountered states of matter, Bose–Einstein condensates are extremely fragile. The slightest interaction with the outside world can be enough to warm them past the condensation threshold, forming a normal gas and losing their interesting properties. It is likely to be some time before any practical applications are developed.

Nevertheless, they have proved to be useful in exploring a wide range of questions in fundamental physics, and the years since the initial discoveries by the JILA and MIT groups have seen an explosion in experimental and theoretical activity. Examples include experiments that have demonstrated interference between condensates due to wave-particle duality,[6] the study of superfluidity and quantized vortices,[7] and the slowing of light pulses to very low speeds using electromagnetically induced transparency.[8] Vortices in Bose-Einstein condensates are also currently the subject of analogue-gravity research, studying the possibility of modeling black holes and their related phenomena in such environments in the lab. Experimentalists have also realized "optical lattices", where the interference pattern from overlapping lasers provides a periodic potential for the condensate. These have been used to explore the transition between a superfluid and a Mott insulator,[9] and may be useful in studying Bose–Einstein condensation in fewer than three dimensions, for example the Tonks-Girardeau gas.

Bose–Einstein condensates composed of a wide range of isotopes have been produced.[10]

Related experiments in cooling fermions rather than bosons to extremely low temperatures have created degenerate gases, where the atoms do not congregate in a single state due to the Pauli exclusion principle. To exhibit Bose–Einstein condensation, the fermions must "pair up" to form compound particles (e.g. molecules or Cooper pairs) that are bosons. The first molecular Bose–Einstein condensates were created in November 2003 by the groups of Rudolf Grimm at the University of Innsbruck, Deborah S. Jin at the University of Colorado at Boulder and Wolfgang Ketterle at MIT. Jin quickly went on to create the first fermionic condensate composed of Cooper pairs.[11]

In 1999, Danish physicist Lene Vestergaard Hau led a team from Harvard University who succeeded in slowing a beam of light to about 17 metres per second and, in 2001, was able to momentarily stop a beam. She was able to achieve this by using a superfluid. Hau and her associates at Harvard University have since successfully transformed light into matter and back into light using Bose-Einstein condensates. Details of the experiment are discussed in an article in the journal Nature, 8 February 2007. [12]

 Atom laser Atomic coherence Bose gas Electromagnetically induced transparency Fermionic condensate Gas in a box Gross-Pitaevskii equation Slow light Superconductivity Superfluid superfluid film Supersolid Tachyon condensation Tonks-Girardeau gas Super-heavy atom Bose-Einstein condensation: a network theory approach

## References

• S. N. Bose, Z. Phys. 26, 178 (1924)
• A. Einstein, Sitz. Ber. Preuss. Akad. Wiss. (Berlin) 1, 3 (1925)
• L.D. Landau, J. Phys. USSR 5, 71 (1941)
• L. Landau (1941). "Theory of the Superfluidity of Helium II". Physical Review 60: 356-358.
• M.H. Anderson, J.R. Ensher, M.R. Matthews, C.E. Wieman, and E.A. Cornell (1995). "Observation of Bose–Einstein Condensation in a Dilute Atomic Vapor". Science 269: 198-201.
• C. Barcelo, S. Liberati and M. Visser (2001). "Analogue gravity from Bose-Einstein condensates". Classical and Quantum Gravity 18: 1137-1156.
• P.G. Kevrekidis, R. Carretero-Gonzlaez, D.J. Frantzeskakis and I.G. Kevrekidis (2006). "Vortices in Bose-Einstein Condensates: Some Recent Developments". Modern Physics Letters B 5.
• K.B. Davis, M.-O. Mewes, M.R. Andrews, N.J. van Druten, D.S. Durfee, D.M. Kurn, and W. Ketterle (1995). "Bose–Einstein condensation in a gas of sodium atoms". Physical Review Letters 75: 3969-3973..
• D. S. Jin, J. R. Ensher, M. R. Matthews, C. E. Wieman, and E. A. Cornell (1996). "Collective Excitations of a Bose–Einstein Condensate in a Dilute Gas". Physical Review Letters 77: 420-423.
• M. R. Andrews, C. G. Townsend, H.-J. Miesner, D. S. Durfee, D. M. Kurn, and W. Ketterle (1997). "Observation of interference between two Bose condensates". Science 275: 637-641..
• M. R. Matthews, B. P. Anderson, P. C. Haljan, D. S. Hall, C. E. Wieman, and E. A. Cornell (1999). "Vortices in a Bose–Einstein Condensate". Physical Review Letters 83: 2498-2501.
• E.A. Donley, N.R. Claussen, S.L. Cornish, J.L. Roberts, E.A. Cornell, and C.E. Wieman (2001). "Dynamics of collapsing and exploding Bose–Einstein condensates". Nature 412: 295-299.
• M. Greiner, O. Mandel, T. Esslinger, T. W. Hänsch, I. Bloch (2002). "Quantum phase transition from a superfluid to a Mott insulator in a gas of ultracold atoms". Nature 415: 39-44..
• S. Jochim, M. Bartenstein, A. Altmeyer, G. Hendl, S. Riedl, C. Chin, J. Hecker Denschlag, and R. Grimm (2003). "Bose–Einstein Condensation of Molecules". Science 302: 2101-2103.
• Markus Greiner, Cindy A. Regal and Deborah S. Jin (2003). "Emergence of a molecular Bose−Einstein condensate from a Fermi gas". Nature 426: 537-540.
• M. W. Zwierlein, C. A. Stan, C. H. Schunck, S. M. F. Raupach, S. Gupta, Z. Hadzibabic, and W. Ketterle (2003). "Observation of Bose–Einstein Condensation of Molecules". Physical Review Letters 91: 250401.
• C. A. Regal, M. Greiner, and D. S. Jin (2004). "Observation of Resonance Condensation of Fermionic Atom Pairs". Physical Review Letters 92: 040403.
• C. J. Pethick and H. Smith, Bose–Einstein Condensation in Dilute Gases, Cambridge University Press, Cambridge, 2001.
• Lev P. Pitaevskii and S. Stringari, Bose–Einstein Condensation, Clarendon Press, Oxford, 2003.
• Amandine Aftalion, Vortices in Bose–Einstein Condensates, PNLDE Vol.67, Birkhauser, 2006.
• Mackie M, Suominen KA, Javanainen J., "Mean-field theory of Feshbach-resonant interactions in 85Rb condensates." Phys Rev Lett. 2002 Oct 28;89(18):180403.

### Notes

1. ^ http://www.livescience.com/history/ap_050822_einstein.html, http://www.lorentz.leidenuniv.nl/history/Einstein_archive/
2. ^ Nikuni, T.; M. Oshikawa, A. Oosawa, and H. Tanaka, (1999). "Bose–Einstein Condensation of Dilute Magnons in TlCuCl3". Physical Review Letters 84: 5868.
3. ^ Demokritov, S.O.; V.E. Demidov, O. Dzyapko, G.A. Melkov, A.A. Serga, B Hillebrands, and A.N. Slavin (2006). "Bose-Einstein condensation of quasi-equilibrium magnons at room temperature under pumping". Nature 443: 430-433.
4. ^ http://www.amazon.com/dp/0521658381/
5. ^ http://nobelprize.org/nobel_prizes/physics/laureates/2001/cornellwieman-lecture.pdf
6. ^ http://cua.mit.edu/ketterle_group/Projects_1997/Interference/Interference_BEC.htm
7. ^ http://www.aip.org/pt/vol-53/iss-8/p19.html
8. ^ http://www.europhysicsnews.com/full/26/article1/article1.html
9. ^ http://qpt.physics.harvard.edu/qptsi.html
10. ^ http://physicsweb.org/articles/world/18/6/1
11. ^ http://physicsweb.org/articles/news/8/1/14/1
12. ^ http://www.nature.com/nature/journal/v445/n7128/index.html