My watch list  

Critical exponent

Critical exponents describe the behaviour of physical quantities near continuous phase transitions. Remarkable about them is that they are universal, i.e. do not depend on details of the physical system, but only on

  • the dimension of the system,
  • the range of the interaction,
  • the spin dimension.

These properties of critical exponents were found in experiments. The experimental results can be theoretically achieved in Mean Field Theory for higher-dimensional systems (4 or more dimensions). The theoretical treatment of lower-dimensional systems (1 or 2 dimensions) is more difficult and requires the Renormalization group.


Phase transitions occour at a certain temperature, called the critical temperature Tc. We want to describe the behaviour of a physical quantity f in terms of a power law around the critical temperature. So we introduce the reduced temperature τ: = (TTc) / Tc, which is zero at the phase transition, and define the critical exponent k.

k\stackrel{def}{=}\lim_{\tau \to 0}{\log f(\tau) \over \log \tau}

This results in the power law we were looking for.

f(\tau) \propto \tau^k,\ \ \tau\approx 0

The most important critical exponents

Above and below Tc the system has two different phases characterized by an order parameter Ψ, which vanishes at and above Tc.

Let us consider the disordered phase (τ > 0), ordered phase (τ < 0 ) and critical temperature (τ = 0) phases separately. Following the standard convention, the critical exponents related to the ordered phase are primed. We have spontaneous symmetry breaking in the ordered phase. So, we will arbitrarily take any solution in the phase.

Ψorder parameter (ρ − ρc)/ρc for the liquid-gas critical point, magnetization for the Curie point,etc.)
τ(T − Tc)/Tc
Cspecific heat; -T\frac{\partial^2 F}{\partial T^2}
Jsource field (e.g. (P − Pc)/Pc where P is the pressure and Pc the critical pressure for the liquid-gas critical point, the magnetic field H for the Curie point )
χthe susceptibility/compressibility/etc.; \frac{\partial \Psi}{\partial J}
ξcorrelation length
dthe number of spatial dimensions
\left\langle \psi(\vec{x}) \psi(\vec{y}) \right\ranglethe correlation function

The following entries are evaluated at J = 0 (except for the δ entry)

Critical exponents for τ > 0 (disordered phase)
Greek letterrelation
αC ~ τ−α
γχ ~ τ−γ
νξ ~ τ−ν
Critical exponents for τ < 0 (ordered phase)
Greek letterrelation
α'C ~ (−τ)−α'
βΨ ~ (−τ)β
γ'χ ~ (−τ)−γ'
ν'ξ ~ (−τ)−ν'
Critical exponents for τ = 0
δJ ~ ψδ
η\left\langle \psi(0) \psi(r) \right\rangle \sim r^{-d+2-\eta}

These relations are accurate close to the critical point in two- and three-dimensional systems. In four dimensions, however, the power laws are modified by logarithmic factors. This problem does not appear in 3.99 dimensions, though.

α = α'
γ = γ'
ν = ν'

The classical (Landau theory aka mean field theory) values are

α = α' = 0
β = 1/2
γ = γ' = 1
δ = 3

If we add derivative terms turning it into a mean field Landau-Ginzburg theory, we get

η = 0
ν = 1 / 2

The most accurately measured value of α is −0.0127 for the phase transition of superfluid helium (the so-called lambda-transition). The value was measured in a satellite to minimize pressure differences in the sample (see here). This result agrees with theoretical prediction obtained by variational perturbation theory (see here or here).

Critical exponents are denoted by Greek letters. They fall into universality classes and obey scaling relations such as


The critical exponents can be computed from conformal field theory.

See also anomalous scaling dimension.

See also

This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Critical_exponent". A list of authors is available in Wikipedia.
Your browser is not current. Microsoft Internet Explorer 6.0 does not support some functions on Chemie.DE